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Chapter: 11th Chemistry : UNIT 11 : Fundamentals of Organic Chemistry

Nomenclature of organic compounds

The International Union of Pure and Applied Chemistry (IUPAC) is the world authority on chemical nomenclature and terminology, naming of new elements in the periodic table standardized methods for measurement; atomic weights, and many other critically-evaluated data.

Nomenclature of organic compounds:

 

The International Union of Pure and Applied Chemistry (IUPAC) is the world authority on chemical nomenclature and terminology, naming of new elements in the periodic table standardized methods for measurement; atomic weights, and many other critically-evaluated data. According to IUPAC recommendations to name any organic compound, it is considered as a derivative of its parent saturated hydrocarbon. The IUPAC name of an organic compound consists of three parts.

prefix + root word + suffix

Root word denotes the number of carbon atoms in the longest continiuous chain in molecules. Prefix denotes the group(s) attached to the main chain which is placed before the root. Suffix denotes the funtional group and is paced after the root word.

Table 11.2 Number of carbons in parent chain and the corresponding root words



Suffix: There are two types of suffix. They are primary suffix and secondary suffix

Primary suffix: It denotes the saturation/ unsaturation of organic compounds. It is added immediately after the root word. Primary suffix for various saturated and unsaturated carbon chains are as follows:

Table 11.3 Primary suffix for various saturated and unsaturated carbon chains


Secondary suffix: It is used to denote the nature of functional group present in the organic compound. It is added to the primary suffix by removig its terminal ‘e’. Secondary suffix names for some functional groups is listed below in table 11.4

Table 11.4 Secondary sufix and prefixes for some functional groups:


Prefix: Substituents that are attached to the parent carbon chain are denoted by adding prefix names before the root word. The prefix names for some common substituents are listed below. If the functional groups are not part of the parent chain, they are considered as substituents. In such cases its prefix name is added before the root word. Prefix names for some functional groups mentioned along with their secondary prefix are listed in table 11.4

Table 11.5 List of substitutents and their Prefix names



 

IUPAC rules for nomenclature of organic compounds

 

The following steps should be followed for naming an organic compound as per IUPAC nomenclature.

1. Choose the longest carbon chain. (Root word). Consider all the other groups attached to this chain as substitutents.

2. Numbering of the longest carbon chain

3. Naming of the substituents (prefixes or suffixes)

4. Arrange the substitutents in the alphabetical order

5. Write the name of the compound as below

"prefix + root word + primary suffix + secondary suffix"








The following are guide lines for writing IUPAC of the organic compound.

 

1. The IUPAC names are always written as single word, with notable exception of organic salts, acids and acid derivatives.

 

2. Commas are used between two adjacent number or letter symbols, and hypens are used to separate numbers and letter symbol in names Eg: 2,2-Dimethyl-3-hexene N,N-Dimethyl methanamide

 

3. Structural prefix such as, meso-, cis-, trans-, are italicised and joined to the name by a hypen. These prefixes are omitted in alphabetising compound names or in capitalising names at the beginning of a sentence.Eg:trans-2-Butene

 

4. Structural prefixes such as di, tri, tetra are treated as a part of the basic name and therefore are neither italicised nor separated by a hypen. These prefixes are not taken into account in alphabetising compound names eg: 4- Ethyl -2,2-dimethyl hexane.

 

5. To name alicyclic compounds , the additional rules should be followed as illustrated in the table 11.x

 

Table 11.6 Rules for naming of alicyclic compounds:








 

In the naming of such compounds a prefix cyclo is added to the word root


 

If only one substituent is present on the ring, then it is not required to give its position


 

If two or more substituents are present on the ring, the numbering of ring is done according to lowest set of locant rule. Alicyclic compounds also follow the numbering rules of acyclic compounds


 

If the ring contains lesser number of carbon atoms than that of alkyl group attached to it, the compound is named as derivative of alkane and the ring is considered as a substituent group to the alkane, otherwise it is named as derivative of cycloalkane


 

If the side chain contains a multiple bond or a functional group, then the alicyclic ring is treated as the substituent irrespective of the size of the ring


 

If the alicyclic ring contains a multiple bond and the side chain contains a functional group the compound is named as derivative of the side chain and the ring is treated as substituent


 

If both ring as well as the side chain contain the functional group, then parent hydrocarbon is decided on the basis of principal group which is further based on preferential order of functional groups


 

If both alicyclic ring and the side chain contain same functional group, the parent hydrocarbon is selected on the basis of number of carbon-atoms in the ring and side chain


 

If more than one alicyclic rings are attached to the single chain of carbon atoms, the compound is named as a derivative of alkane and alicyclic rings are treated as substituent irrespective of the number of atom in the ring or chain


 

If the alicyclic ring is directly attached to the benzene ring the compound is named as a derivative of benzene


 

If the alicyclic ring has a functional group along with some substituent on the ring, then the appropriate prefixes and suffixes are used to represent such groups, and numbering is done in such a way that the functional group is not counted for word root rather appropriate suffixes are used to represent such groups


 

NOMENCLATURE OF AROMATIC COMPOUNDS:

 

An aromatic compound consists of two parts nucleus and side chain

 

(A) Nucleus: The benzene ring present in aromatic compound is called nucleus. It is represented as follows


 

(B) Side chain: Alkyl or any other aliphatic group attached to the benzene nucleus by replacing one or more hydrogen atom is called the side chain


If one hydrogen atom, (or) two hydrogen atoms or three hydrogen atoms are replaced in the benzene ring by some other groups, they are termed as mono substituted, di substituted or tri substituted derivative respectively.

 

Example


If more than one hydrogen atom of benzene ring is replaced by some other atom or group, then their position is mentioned by Arabic numerals 1,2,3 ….. In case of disubstitution, respective position of two groups can also be mentioned as follows.

ortho - adjacent; represented as - o

meta - alternate; represented as - m

Para - opposite; represented as - p

 

Aromatic compounds are basically of two types:

 

1. Nuclear substituted aromatic compounds: These are the compounds in which the functional group is directly attached to the benzene ring. They are named as derivatives of benzene.



Nuclear substituaed aramatic Halogen derivatives compounds.


 

2. Side chain substituted aromatic compounds: These are the compounds in which the functional group is present in the side chain of the benzene ring. These are named as phenyl derivatives of the corresponding aliphatic compounds.

Side chain substituted


Aryl groups


Selection of parent hydrocarbon out of side chain and benzene ring is based on (more or less) some rule as for the alicyclic compounds.

Table 11.3.1. 2







 

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