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Chapter: 11th 12th std standard Class Organic Inorganic Physical Chemistry Higher secondary school College Notes

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Group - 15 Elements - The Nitrogen Family

Group - 15 Elements - The Nitrogen Family
The group 15 (VA) elements are nitrogen, phosphorus, arsenic, antimony and bismuth. Elements : Nitrogen, Phosphorus , Arsenic , Antimony , Bismuth.


GROUP - 15 ELEMENTS - THE NITROGEN FAMILY


The group 15 (VA) elements are nitrogen, phosphorus, arsenic, antimony and bismuth.

1.     Nitrogen is a gas. It makes up 78% of the earth's atmosphere by volume.

2.     Phosphorus is the most abundant element of 15th group, accounting for 0.10% of the mass of the earth's crust.

3.     Arsenic is also used to make pesticides and semi conductors, such as GeAs.

4.           Bismuth is a silvery solid. Bismuth compounds are present in some pharmaceuticals such as Pepto-bismol.

5.           The natural abundance of As, Sb and Bi in the earth's crust is relatively low.

General trends

Electronic configuration: All these elements have general electronic  configuration of ns2 np3.

Electronic configuration of group 15 elements

 

Nitrogen -

Atomic Number :  7  Electronic Configuration  :  [He] 2s2 2p3  Group Number : 15   Periodic Number  :  2

 

Phosphorus  -

Atomic Number :  15  Electronic Configuration  :  [Ne] 3s2 3p3  Group Number : 15   Periodic Number  : 3

 

Arsenic  -

Atomic Number :  33  Electronic Configuration  :  [Ar] 3d10 4s2 4p3 Group Number : 15   Periodic Number  :  4

 

Antimony  -

Atomic Number :  51   Electronic Configuration  :  [Kr] 4d10 5s2 5p3  Group Number : 15   Periodic Number  : 5 

 

Bismuth  -

Atomic Number :  83    Electronic Configuration  : [Xe] 4f14 5d10 6s2 6p3  Group Number : 15   Periodic Number  :  6

 

 

Compounds of Phosphorus

a)  Halides of Phosphorus

Phosphorus combines with allthehalogens forming phosphorus halides which are all covalent compounds. Phosphorus chlorides are more important. Tri and pentachlorides of phosphorus are most common.


b) Oxides of phosphorus

Phosphorus trioxide P2O3 or P4O6

It is obtained by the combustion of phosphorus in a limited supply of air.

 

4P + 3O2  2P2O3

c)    Oxy-Acids of Phosphorus

  Phosphorus acid - H3PO3

It is prepared by the action of cold water on phosphorus (III) oxide or phosphorus (III) chloride.

 

d)    Phosphine - PH3

Phosphine is the best known hydride of phosphorus.

 

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