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Chapter: 11th 12th std standard Class Organic Inorganic Physical Chemistry Higher secondary school College Notes

Experiments to prove particle and wave property of Electrons

Experiments to prove particle and wave property of Electrons
a) Verification of Wave character i) Davisson and Germer's Experiment ii) Thomson's experiment b) Verification of the particle character

Experiments to prove particle and wave property of Electrons

a)        Verification of Wave character

i)          Davisson and Germer's Experiment

 

In 1927 Davisson and Germer observed that, a beam of electrons obtained from a heated tungsten filament is accelerated by using a high positive potential. When this fine beam of accelerated electron is allowed to fall on a large single crystal of nickel, the electrons are scattered from the crystal in different

directions. The diffraction pattern so obtained is similar to the diffraction pattern obtained by Bragg's experiment on diffraction of X-rays from a target in the same way (Fig.).

diffraction experiment by Davisson and Germer

 

Since X-rays have wave character, therefore, the electrons must also have wave character associated with them. Moreover, the wave length of the electrons as determined by the diffraction experiments were found to be in agreement with the values calculated from de-Broglie equation.

 

From the above discussion, it is clear that an electron behaves as a wave.


ii)        Thomson's experiment

 

G.P. Thomson in 1928 performed experiments with thin foil of gold in place of nickel crystal. He observed that if the beam of electrons after passing through the thin foil of gold is received on the photographic plate placed perpendicular to the direction of the beam, a diffraction pattern is observed as before (Fig.). This again confirmed the wave nature of electrons.


b)       Verification of the particle character

 

The particle character of the electron is proved by the following different experiments:-

 

i)          When an electron strikes a zinc sulphide screen, a spot of light known as scintillation is produced. A scintillation is localized on the zinc sulphide screen. Therefore the striking electron which produces it, also must be localized and is not spread out on the screen. But the localized character is possessed by particles. Hence electron has particle character.

 

ii)       Experiments such as J.J.Thomson's experiment for determination of the ratio of charge to mass (i.e. e/m) and Milliken oil drop experiment for determination of charge on electron also show that electron has particle character.

 

iii)     The phenomenon of Black body radiation and Photoelectric effect also prove the particle nature of radiation.

 

 

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11th 12th std standard Class Organic Inorganic Physical Chemistry Higher secondary school College Notes : Experiments to prove particle and wave property of Electrons |


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