Home | | Chemistry | | Chemistry | Dual Property of an Electron

Chapter: 11th 12th std standard Class Organic Inorganic Physical Chemistry Higher secondary school College Notes

| Study Material, Lecturing Notes, Assignment, Reference, Wiki description explanation, brief detail |

Dual Property of an Electron

Dual Property of an Electron
In case of light, some phenomena like interference, diffraction etc., can be explained if light is supposed to have wave character. However certain other phenomena such as black body radiation and photo electric effect can be explained only if it is believed to be a stream of photons i.e., has particle character.

DUAL PROPERTY OF AN ELECTRON

 

In case of light, some phenomena like interference, diffraction etc., can be explained if light is supposed to have wave character. However certain other phenomena such as black body radiation and photo electric effect can be explained only if it is believed to be a stream of photons i.e., has particle character. Thus light is said to have a dual character. Such studies on light were made by Einstein in 1905.

 

Louis de Broglie, a French Physicist, in 1924, advanced the idea that like photons, all material particles such as electron, proton, atom, molecule, a piece of chalk, a piece of stone or iron ball possessed both wave character as well as particle character. The wave associated with a particle is called a matter wave.

 

Difference between a particle and a wave

 

The concept of a particle and a wave can be understood by the different points of distinction between them.

PARTICLE

 

1. A particle occupies a well-defined  position in space i.e a particle is      localized in space e.g. a grain of  sand, a cricket ball etc.

 

2. When a particular space is occupied by one particle, the same space cannot be occupied simultaneously by any other particle. In other words, particles do not interfere.

 

3. When a number of particles are present in a given region of space, their total value is equal to their sum i.e it is neither less nor more.

 

 

WAVE

         

1. a wave is spread out in space e.g. on throwing a stone in a pond of water, the waves start moving out in the form of concentric circles. Similarly, the sound of the speaker reaches everybody in the audience. Thus a wave is delocalized in space.

         

2. Two or more waves can coexist in the same region of space and hence interfere.

         

3. When a number of waves are present in a given region of space, due to interference, the resultant wave can be larger or smaller than the individual waves i.e. interference may be constructive or destructive.

 

Experiments to prove particle and wave property of Electrons

a)        Verification of Wave character

i)          Davisson and Germer's Experiment

 

In 1927 Davisson and Germer observed that, a beam of electrons obtained from a heated tungsten filament is accelerated by using a high positive potential. When this fine beam of accelerated electron is allowed to fall on a large single crystal of nickel, the electrons are scattered from the crystal in different

directions. The diffraction pattern so obtained is similar to the diffraction pattern obtained by Bragg's experiment on diffraction of X-rays from a target in the same way (Fig.).


diffraction experiment by Davisson and Germer

 

Since X-rays have wave character, therefore, the electrons must also have wave character associated with them. Moreover, the wave length of the electrons as determined by the diffraction experiments were found to be in agreement with the values calculated from de-Broglie equation.

 

From the above discussion, it is clear that an electron behaves as a wave.

ii)        Thomson's experiment

 

G.P. Thomson in 1928 performed experiments with thin foil of gold in place of nickel crystal. He observed that if the beam of electrons after passing through the thin foil of gold is received on the photographic plate placed perpendicular to the direction of the beam, a diffraction pattern is observed as before (Fig.). This again confirmed the wave nature of electrons.


b)       Verification of the particle character

 

The particle character of the electron is proved by the following different experiments:-

 

i)          When an electron strikes a zinc sulphide screen, a spot of light known as scintillation is produced. A scintillation is localized on the zinc sulphide screen. Therefore the striking electron which produces it, also must be localized and is not spread out on the screen. But the localized character is possessed by particles. Hence electron has particle character.

 

ii)       Experiments such as J.J.Thomson's experiment for determination of the ratio of charge to mass (i.e. e/m) and Milliken oil drop experiment for determination of charge on electron also show that electron has particle character.

 

iii)     The phenomenon of Black body radiation and Photoelectric effect also prove the particle nature of radiation.

 

 

Study Material, Lecturing Notes, Assignment, Reference, Wiki description explanation, brief detail


Copyright © 2018-2020 BrainKart.com; All Rights Reserved. Developed by Therithal info, Chennai.