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Chapter: 11th Chemistry : Basic Concepts of Chemistry and Chemical Calculations

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Avogadro Number

The total number of entities present in one mole of any substance is equal to 6.022 x 10 pow(23).

Avogadro Number:

 

The total number of entities present in one mole of any substance is equal to 6.022 x 1023. This number is called Avogadro number which is named after the Italian physicist Amedeo Avogadro who proposed that equal volume of all gases under the same conditions of temperature and pressure contain equal number of molecules. Avogadro number does not have any unit.

 

In a chemical reaction, atoms or molecules react in a specific ratio. Let us consider the following examples

 

Reaction 1     :    C + O2 CO2

Reaction 2     :    CH4 + 2 O2  → CO2 + 2 H2O

 

In the first reaction, one carbon atom reacts with one oxygen molecule to give one carbon dioxide molecule. In the second reaction, one molecule of methane burns with two molecules of oxygen to give one molecule of carbon dioxide and two molecules of water. It is clear that the ratio of reactants is based on the number of molecules. Even though the ratio is based on the number of molecules it is practically difficult to count the number of molecules. Because of this reason it is beneficial to use 'mole' concept rather than the actual number of molecules to quantify the reactants and the products. We can explain the first reaction as one mole of carbon reacts with one mole of oxygen to give one mole of carbon dioxide and the second reaction as one mole of methane burns with two moles of oxygen to give one mole of carbon dioxide and two moles of water. When only atoms are involved, scientists also use the term one gram atom instead of one mole.

Lorenzo Romano Amedeo Carlo Avogadro (1776-1856)

He is known for the Avogadro's hypothesis. In honour of his contributions, the number of fundamental particles in a mole of substance was named as Avogadro number. Though Avogadro didn't predict the number of particles in equal volumes of gas, his hypothesis did lead to the eventual determination of the number as 6.022 x 1023 Rudolf Clausius, with his kinetic theory of gases, provided evidence for Avogadro's law.

 

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Study Material, Lecturing Notes, Assignment, Reference, Wiki description explanation, brief detail

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