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Miller Indices - Procedure for finding and Important Features

Miller introduced a system to designate a plane in a crystal. He introduced a set of three numbers to specify a plane a plane in a crystal. This set of three numbers is known as Miller Indices of the concerned plane.

Miller Indices

Miller introduced a system to designate a plane in a crystal. He introduced a set of three numbers to specify a plane a plane in a crystal. This set of three numbers is known as Miller Indices of the concerned plane.

Procedure for finding Miler Indices

·        Determine the intercepts of the plane along the axes X, Y and Z in terms of the Lattice Constant a, b, c.

·        Determine the reciprocals of these numbers.

·        Find the least common denominator (LCD) and multiply each by this lcd. The result is written in the form (hkl) and is called the Miller Indices of the plane.

Example

Let the plane have intercepts 4, 1 and 2 on the three axes. The reciprocals are ¼ , 1 and ½. Multiplying each by 4, we get 1, 4 and 2. Hence (142) are the Miller Indices of the plane.

Plane ABC (figure 1.1.5) has intercepts of 2 axial units on X-axis, 2 axial units on Y-axis and 1 axial unit on Z-axis.

The reciprocals are ½,1/2 and 1. The LCM is 2.

Multiplying each by , we get 1,1,2. Hence the Miller Indices of the plane are (112)

Important Features of Miller Indices

When a plane is parallel to any axis, the intercept of the plane on that axis is infinity. Hence The Miller Indices for that axis zero.

If a plane cuts an axis on the negative side of the origin, corresponding index is negative.

The indices (hkl) do not define a particular plane but a set of parallel planes. Thus the planes whose intercepts are 1, 1, 1;2, 2;-3,-3,-3 etc. are all represented by the same set of Miller Indices.

1 (a) Points to ponder

The Miller Indices should be enclosed only in this bracket.

There should not be any commas in between the numbers.

If the Miller Indices is say (2 6 3) means it should be read as two six three, and not as two hundred and sixty three.

The direction of plane can be represented by enclosing the Miller Indices in a square bracket. For example [2 6 3]

To represent the family of planes we can use this bracket i.e. ->

Putting a bar over the numbers can represent negative Miller Indices For an example (2 6 3) represents the plane with intercepts on negative axis, positive Y-axis and negative Z-axis.

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