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Properties of Glucose, Fructose and Galactose:
· Can be solid or liquid
· Melting Point: 294.8˚F(146˚C)
· Density: 1.54 g/cm³
· Weight: 180.16 g/mol
· Soluble in water and acetic acid
Fructose has a higher solubility than other sugar; therefore, it is harder for fructose to crystallize from an aqueous solution.
· White colour Powder
· Melting point of fructose is 103°C
· The compound of fructose has a molar mass of 180.16 mol/g.
· Density of 1.69g/cm2.
· Weight 180.16 g/mol
· Soluble in water
· White powder.
· Solubility in water : 680 g/L.
· Melting point 167 °C
· Weight 180.156 g/mol.
· Soluble in water.
Both glucose and fructose behave as weak acids and form salts with Ca(OH)2 (lime water).
Glucose and Fructose form penta acetyl derivative when treated with acetic anhydride.
Glucose and fructose react with methanol in the presence of dry HCl gas to give ethers known as methyl glucoside and methyl fructoside, respectively.
i. Sodium amalgum reduces glucose into sorbitol and fructose into a mixture of sorbitol and mannitol. Similarly, it reduces fructose into a mixture of sorbitol and mannitol.
a.Both are reduced to n-hexane by HI / red ‘P’.
b.Galactose on reduction with Na/Hg, gives dulcitol ( and with HI/red P, n-hexane will be obtained.
a. Glucose is oxidized by mild oxidizing agents like bromine water into gluconic acid. Strong oxidizing agents like conc. HNO3 oxidize glucose into gluconic acid.
b. Fructose is not oxidised by mild oxidising agents. But strong oxidising agents like conc. HNO3 split fructose into a mixture of trihydroxy glutaric, tartaric and glycollic acids.
c. Galactose on oxidation with mild oxidizing agent such as bromine water, gives galactonic acid. On oxidation with strong oxidizing agents like HNO3, it gives galactaric (or) mucic acid. This acid is insoluble in water and hence this reaction is used as a test for galactose. On oxidation with O2/Pt-C (as in glucose, after protecting the –CHO group into ispropylidene group) it gives galacturonic acid.
Both glucose and fructose reduce Tollen’s reagent into silver mirror.
Both glucose and fructose reduce Fehling’s solution into red cuprous oxide.
Both glucose and fructose reduce Barfoed’s and Benedict’s reagents into red cuprous oxide as in the case of Fehling’s solution.
Glucose+CuO‚Gluconic acid + Cu2O ↓
Fructose+CuO‚Tartaric acid+glycollic acid+Cu2O↓
Since both glucose and fructose reduce all these four reagents (Tollen’s, Fehling’s, Benedict’s and Barfoed’s reagent), these sugars are known as reducing sugars.
· Both glucose and fructose form oximes with hydroxylamine.
· With NH2OH, galactose forms galactoseoxime.
Both glucose and fructose form cyanohydrins with HCN
Both glucose and fructose when heated with conc. HCl give laevulic acid.
When warmed with conc. alkali sugars first turn yellow, then brown and finally resinify. But in the presence of dilute. alkali glucose and fructose give a mixture of D-glucose, D-mannose and D-fructose. This is known as Lobry de Bruyn - van Ekenstein rearrangement. This occurs through enediol.
Both glucose and fructose react with excess of phenyl hydrazine to give same type of osazone. Glucose and fructose have structural difference with respect to only first two carbon atoms, which are involved in osazone formation. The configurations in the rest of the carbon atoms are similar to both glucose and fructose. Hence they form similar osazone.
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