RANCIDITY
Fats and oils undergo certain
undesirable changes during storage which result in spoilage. The major spoilage
of fats and oils is rancidity.
Rancidity refers to the development of disagreeable odour
and flavour in fats and oils owing to specified chemical reaction such as
oxidation and hydrolysis.
Hydrolysis is the decomposition of fats into free fatty acid
and glycerol by enzymes in the presence of moisture. These free fatty acids
released are responsible for the unpleasant flavour and odour.
During oxidation, oxygen is added to the unsaturated linkage
and this results in the formation of peroxides. These peroxides decompose to
yield aldehyde and ketones which are responsible for the pronounced off
flavour. Rancidity may also be caused by the absorption of odour and action of
micro organism and enzymes.
Prevention of rancidity :
1.
Storage in coloured glass containers
prevent oxidation of fats by rays of light.
2.
Vacuum packaging retards rancidity
by excluding oxygen.
3.
Naturally occurring antioxidants
like vitamin C, b
carotene and vitamin E protect against rancidity.
4.
Synthetic antioxidants like
butylated hydroxy anisole (BHA), butylated hydroxy toluene (BHT) and
propylgallate can also be added to prevent rancidity.
Fats And Oils
Fats are an important component of
the diet and is present naturally in many foods. Fats are solid at room
temperature while oils are liquid. Fats in the diet can be of two kinds viz.,
the visible and the invisible fat.
Invisible fats are those present
inherently in foods. Example of food containing appreciable quantities of
invisible fat include meat, poultry, fish, dairy products, eggs, nuts and
seeds.
Visible fats are those fats that are
made from these products. They are cooking oils, salad oils, butter, ghee and
margarine.
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