METHODS
OF AERATION
Two general methods may
be used for the aeration of water. The most common in industrial use is the
water-fall aerator. Through the use of spray nozzles, the water is broken up
into small droplets or a thin film to enhance countercurrent air contact.
In the air diffusion
method of aeration, air is diffused into a receiving vessel containing
counter-current flowing water, creating very small air bubbles. This ensures
good air-water contact for "scrubbing" of undesirable gases from the
water.
Water-Fall
Aerators
Many variations of the water-fall principle are used
for this type of aeration. The simplest configuration employs a vertical riser
that discharges water by free fall into a basin (Figure 4-2). The riser usually
operates on the available head of water. The efficiency of aeration is improved
as the fall distance is increased. Also, steps or shelves may be added to break
up the fall and spread the water into thin sheets or films, which increases
contact time and aeration efficiency.
Coke tray and wood or plastic slat water-fall
aerators are relatively similar in design and have the advantage of small space
requirements.
Coke tray aerators are widely used in iron and
manganese oxidation because a catalytic effect is secured by contact of the
iron/manganese-bearing water with fresh precipitates. These units consist of a
series of coke-filled trays through which the water percolates, with additional
aeration obtained during the free fall from one tray to the next.
Wood or plastic slat tray aerators are similar to
small atmospheric cooling towers. The tray slats are staggered to break up the
free fall of the water and create thin films before the water finally drops
into the basin.
Forced draft water-fall aerators (see Figure 4-3)
are used for many industrial water conditioning purposes. Horizontal wood or
plastic slat trays, or towers filled with packing of various shapes and
materials, are designed to maximize disruption of the falling water into small
streams for greater air-water contact. Air is forced through the unit by a blower
which produces uniform air distribution across the entire cross section, cross
current or countercurrent to the fall of the water. Because of these features,
forced draft aerators are more efficient for gas removal and require less space
for a given capacity.
Air
Diffusion Aerators
Air diffusion systems aerate by pumping air into
water through perforated pipes, strainers, porous plates, or tubes. Aeration by
diffusion is theoretically superior to water-fall aeration because a fine
bubble of air rising through water is continually exposed to fresh liquid
surfaces, providing maximum water surface per unit volume of air. Also, the
velocity of bubbles ascending through the water is much lower than the velocity
of free-falling drops of water, providing a longer contact time. Greatest
efficiency is achieved when water flow is countercurrent to the rising air
bubbles.
APPLICATIONS
In industrial water
conditioning, one of the major objectives of aeration is to remove carbon
dioxide. Aeration is also used to oxidize soluble iron and manganese (found in
many well waters) to insoluble precipitates. Aeration is often used to reduce
the carbon dioxide liberated by a treatment process. For example, acid may be
fed to the effluent of sodium zeolite softeners for boiler alkalinity control.
Carbon dioxide is produced as a result of the acid treatment, and aeration is
employed to rid the water of this corrosive gas. Similarly, when the effluents
of hydrogen and sodium zeolite units are blended, the carbon dioxide formed is
removed by aeration.
In the case of cold lime softening, carbon dioxide
may be removed from the water before the water enters the equipment. When
carbon dioxide removal is the only objective, economics usually favor removal
of high concentrations of carbon dioxide by aeration rather than by chemical
precipitation with lime.
Air stripping may be
used to reduce concentrations of volatile organics, such as chloroform, as well
as dissolved gases, such as hydrogen sulfide and ammonia. Air pollution
standards must be considered when air stripping is used to reduce volatile
organic compounds.
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