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Chapter: 7th Science : Term 3 Unit 3 : Polymer Chemistry

Glass : Types and Uses

Glass can be found wherever we look; a glass window or glass mirror or glass light bulb. Glass is one of the world’s oldest and most versatile human created materials.

Glass : Types and Uses

Glass can be found wherever we look; a glass window or glass mirror or glass light bulb. Glass is one of the world’s oldest and most versatile human created materials. Glass is the only material that can be recycled over and over again without losing its quality. Glass is bit of a riddle. It is hard enough to protect as, but it shatters with incredible ease. It is made from opaque sand, yet, it is completely transparent. Most surprisingly, it behaves like a solid material, but it is also a sort of weird liquid in disguise!

Glass is prepared by heating (SiO2) silicon-di-oxide until it melts, say to about 1700◦C and Sodium Carbonate is added to it. Then it is cooled down really fast. When SiO2 silicon-di-oxide melts, the silicon and oxygen atoms break out of their crystal structure. If we cooled it slowly, the atoms would slowly line up back into their crystalline arrangement. But if we cool the liquid fast enough, the atoms of the silica will be halted in their tracks, they won’t have time to line up, and they will be stuck in any old arrangement, with no order to the arrangement of the atoms. We call materials like this as amorphous. At this stage, glass is linear in arrangement inorganic in nature and has a structure very similar to glass and they are considered as polymers.

In a commercial glass plant, sand is mixed with waste glass (obtained from recycling collections), soda ash (sodium carbonate) and limestone (calcium carbonate) and heated in a furnace. The soda ash reduces the sand’s melting point and produces a kind of glass that would dissolve in water. The limestone is added to stop that happening. The end product is called soda-lime-silica glass. It is the ordinary glass we see all around us.

Usually, other chemicals are added to change the appearance or properties of the finished glass. For example, iron and chromium based chemicals are added to the molten sand to make green-tinted glass.

Oven-proof borosilicate glass (widely sold under the trademark PYREX) is made by adding boron oxide to the molten mixture.

Adding lead oxide makes from a sandwich or laminate of multiple layers of glass and plastic bonded together.

Toughened glass used in car winds hields is made by cooling molten glass very quickly to make it much harder.


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