Metal
displacement : (Predicting whether a metal will displace another metal from its
salt solution or not).
As already shown, the metals near the bottom of
the electrochemical series are strong reducing agents and are themselves
oxidised to metal ions. On the contrary, the metal lying higher up in the
series are strong oxidising agents and their ions are readily reduced to the
metal itself. For example, zinc
lying down below the series is oxidised to Zn2+ ion, while copper
which is higher up in the series is produced by reduction of Cu2+
ion.
Zn -- -- -- > Zn2+ + 2e-
Cu2+ + 2e-
-- -- -- > Cu ¯
Thus when zinc is placed in CuSO4
solution, Cu metal gets precipitated. In general we can say that a metal lower
down the electrochemical series can precipitate the one higher up in the
series.
Silver cannot precipitate Cu from CuSO4
solution, since both metals have positions higher up in the series and are
strong oxidising agents.
Hydrogen
displacement : (Predicting whether a metal will displace hydrogen from a dilute
acid solution.)
Any metal above hydrogen in the electrochemical
series is a weaker reducing agent than hydrogen and will not convert H+
to H2. This explains why Zn lying below hydrogen reacts with dil. H2SO4
to liberate H2, while Cu lying above hydrogen does not react.
Zn + 2H+ (dil.H2SO4)
-- -- -- > Zn2+ + H -
Cu + 2H+ (dil. H2SO4
) -- --- X-X -X----à Cu2+
+ H
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